The whites colour catcher will remove most of the colour run but in my experience you probably won't get back to the original white and may feel it's still a bit 'grubby' looking. If it was the dress that dyed the collar then it's probably not worth doing as it will happen each time you wash it. Don't despair though, you can always accessorise with a scarf to cover the damage.
I always add bleach in the fabric softener part! Not loads but a good squirt!! Always has my whites really white! And I always do it in a white wash xx
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